期刊
ORGANIC LETTERS
卷 20, 期 13, 页码 3933-3937出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01510
关键词
-
资金
- National Natural Science Foundation of China [21672032]
- Fundamental Research Funds for the Central Universities [2412017QD013]
The present work deals with a challenge in the synthesis of aryltrifluoromethyliodanes (ArICF3X) and develops a direct route to PhICF3Cl via a simple ligand-exchange reaction of PhI(OCOCF3)(2), Me3SiCF3, and NaCl for the first time. The I-Cl bond length in PhICF3Cl supports its iodonium character, which enables an enhanced CF3-transfer capability in electrophilic S-, O-, N-, and C- trifluoromethylations as well as in catalyst-free trifluoromethylation-cyclizations of arylisonitriles.
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