期刊
ORGANIC LETTERS
卷 20, 期 13, 页码 3875-3878出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01462
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资金
- Junta de Extremadura
- FEDER [IB16095]
Enols are used for the first time in a condensation with aldehydes and isocyanides to selectively give three- or pseudo-four-component adducts, depending on the reaction conditions. These new transformations have proven to be a convenient alternative for the synthesis of biologically relevant pyrrolidinones containing peptidic or pseudo-peptidic groups on carbon 3. More importantly, this work attests to the utility of heterocyclic enols containing conjugated electron withdrawing groups as useful reagents in isocyanide-based multi component reactions.
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