期刊
ORGANIC LETTERS
卷 20, 期 3, 页码 574-577出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03688
关键词
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资金
- European Research Council (ERC) under the European Union's Horizon research and innovation programme [639170]
- LabEx Chemistry of Complex Systems
- French government
A general, Bronsted acid catalyzed method for the room temperature, nucleophilic ring opening of donor acceptor cyclopropanes in fluorinated alcohol solvent, HFIP, is described. Salient features of this method include an expanded cydopropane scope, including those bearing single keto-acceptor groups and those bearing electron-deficient aryl groups. Notably, the catalytic system proved amenable to a wide range of nucleophiles including, arenes, indoles, azides, diketones, and alcohols.
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