期刊
ORGANIC LETTERS
卷 20, 期 9, 页码 2792-2795出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01101
关键词
-
资金
- NSFC [21702199]
- China Postdoctoral Science Foundation [2017M612075]
The first catalytic enantioselective decarboxylative propargylation/hydroamination reaction of ethynyl benzoxazinanones with malononitriles enabled by organo/copper cooperative catalysis was established. Various 3-indolin-malononitrile derivatives, displaying a high tolerance for functional groups, could be obtained in good yields with high levels of enantioselectivity (up to 85% yield, 96:4 er). More importantly, this organo/metal cooperative catalytic system will provide a powerful synthetic strategy for new reaction development.
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