期刊
ORGANIC LETTERS
卷 20, 期 3, 页码 538-541出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03620
关键词
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资金
- National Science Foundation [CHE-1362281, CHE-1531620, CHE-1626172]
- Direct For Mathematical & Physical Scien [1531620] Funding Source: National Science Foundation
At 2.5 mol % loadings using reaction temperatures between 30-55 degrees C, ortho-functionalized diaryl diselenides are highly effective organocatalytic oxidants for aerobic redox dehydrative amidic and peptidic bond formation using triethyl phosphite as a simple terminal reductant. This simple-to-perform organocatalytic reaction relies on the ability of selenols to react directly with dioxygen in air without recourse to metal catalysts. It represents an important step toward the development of a general, economical, and benign catalytic redox dehydration protocol.
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