期刊
ORGANIC LETTERS
卷 20, 期 15, 页码 4691-4694出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02017
关键词
-
资金
- Samsung Science and Technology Foundation [SSTF-BA1601-12]
Exclusively alpha- and highly E/Z-selective hydroalkylation of ynone, ynoate, and ynamide was achieved via photoredox mediated Ni/Ir dual catalysis with high atom and step economy, producing trisubstituted enones, which are versatile synthetic building blocks. The developed reaction selectively delivered the alpha/Z isomer, which is complementary to the previously reported beta-alkylation processes. The trisubstituted enones could be transformed to more valuable compounds via post-functionalization.
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