期刊
ORGANIC LETTERS
卷 20, 期 7, 页码 1974-1977出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00518
关键词
-
资金
- National Natural Science Foundation of China [NSFC21502232, NSFC21572272]
A cascade three-component iodoazidation of para-quinone methides to construct spiro[4.5]deca-6,9-dien-8-ones under mild conditions has been developed. The chemoselective 1,6-addition of azide radical triggered a regioselective 5-exo-dig cyclization/radical coupling sequence, enabling C-N, C-C, and C-I bond formations in a one-pot procedure with high efficiency.
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