期刊
ORGANIC LETTERS
卷 20, 期 3, 页码 542-545出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03621
关键词
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资金
- Novartis
- NSF [GOALI SusChEM 1566212]
- Division Of Chemistry [1566212] Funding Source: National Science Foundation
Complexation of ca. 1000 ppm Pd(OAc)(2) with the ligand HandaPhos (1-1.5:1) leads to a precatalyst that efficiently mediates Sonogashira couplings in aqueous nano micelles under very mild conditions. Neither copper nor organic solvent is required in the reaction medium, and the product can be isolated directly from the reaction flask, leaving behind a reaction mixture that can be recycled without additional additives.
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