期刊
ORGANIC LETTERS
卷 20, 期 6, 页码 1580-1583出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00325
关键词
-
资金
- National Institutes of Health [GM-58160, GM-122483]
- National Science Foundation [CHE 9808061]
Two catalyst systems are described, which together provide mild and general conditions for the Pd-catalyzed C-O cross-coupling of primary alcohols. For activated substrates, such as electron-deficient aryl halides, the commercially available ligand L2 promotes efficient coupling for a variety of alcohol nucleophiles. In the case of unactivated electrophiles, such as electron-rich aryl halides, the new ligand L8 was developed to improve these challenging C-O bond-forming reactions.
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