期刊
ORGANIC LETTERS
卷 20, 期 10, 页码 3096-3100出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01152
关键词
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资金
- National Natural Science Foundation of China [21302169, 21602202, 21602203]
- Program for Innovative Research Team of Zhejiang Sci-Tech University [13060052-Y]
- Zhejiang Provincial Top Key Academic Discipline of Chemical Engineering and Technology of Zhejiang Sci-Tech University
A gold-catalyzed cascade cycloisomerization/ring-opening reaction of allenyl ketones bearing a cyclopropyl moiety with a wide variety of alcohols or ketones is developed. This reaction involves an unprecedented 1,2-gold carbene transfer to provide regioselective and modular access to tri- or tetrasubstituted furans in moderate to high yields and with broad substrate tolerability.
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