期刊
ORGANIC LETTERS
卷 20, 期 12, 页码 3553-3556出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01323
关键词
-
资金
- JSPS KAKENHI [JP 15H05485, JP 17H06092]
A palladium-catalyzed benzylic substitution of tert-butyl diarylmethyl carbonates with a pinacol-derived H-phosphonate proceeds to deliver the corresponding benzylic phosphorylated products in good yields. Moreover, the asymmetric synthesis is possible via a Pd/(R-p,R-p')-(S)-Mandyphos-catalyzed kinetic resolution-DYKAT (dynamic kinetic asymmetric transformation) sequence, and optically active alpha-chiral diarylmethylphosphonates are obtained with synthetically useful yields and enantiomeric ratios (up to 50% and 92:8 er).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据