期刊
ORGANIC LETTERS
卷 20, 期 3, 页码 624-627出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03753
关键词
-
资金
- National Natural Science Foundation of China [21274012, 21322401]
- 111 project [B07012]
- Beijing Institute of Technology [1750012331710]
An organo rare-earth metal complex has been employed as a highly efficient nucleophile in Ni(0)-catalyzed C-O bond functionalization. The optimized catalytic system which consists of Ni(cod)(2), PCy3, and t-BuONa could smoothly convert 1 equiv of naphthyl ethers to alkylated naphthalene analogues with 0.4 equiv of Ln-(CH2SiMe3)(3)(THF)(2), delivering good to excellent yields. The reaction system could also activate the ArCH2-O bond with mild base.
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