期刊
ORGANIC LETTERS
卷 20, 期 2, 页码 489-492出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03922
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资金
- National Natural Science Foundation of China [21662021, 21402071]
- Science and Technology Planning Project of Yunnan Province [2017FB016]
A copper-catalyzed decarboxylative disulfonylation of alkynyl carboxylic acids with sulfinic acids in aqueous solution has been developed. The reaction provides a straightforward and practical access to (E)-1,2-disulfonylethenes, which are important building blocks in synthetic organic chemistry, and exhibits a good functional group tolerance and excellent stereoselectivity. A possible mechanism for the transformation is proposed.
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