期刊
ORGANIC LETTERS
卷 20, 期 7, 页码 2015-2019出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00560
关键词
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资金
- JSPS KAKENHI [17H03970, 16K08160]
- Hokuriku Bank, Ltd.
- Grants-in-Aid for Scientific Research [17H03970, 16K08160] Funding Source: KAKEN
A new triazine-based oxidizing reagent, 2-hydroperoxy-4,6-diphenyl-1,3,5-triazine (Triazox), has been developed. The reagent can be synthesized from inexpensive starting materials and is a bench-stable solid that is isolable in pure form. Epoxidation of alkenes possessing acid-sensitive functionalities using Triazox proceeded in good to excellent yields. The accompanying nonacidic triazinone coproduct can be easily removed by filtration. These features indicate that Triazox is a practically useful oxidizing reagent.
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