期刊
ORGANIC LETTERS
卷 20, 期 7, 页码 2042-2045出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00583
关键词
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资金
- JSPS KAKENHI [JP17H06442]
- Graduate Program for Leaders in Life Innovation (GPLLI)
- JSPS
A hybrid catalysis that comprises an acridinium photoredox catalyst, a thiophosphate organocatalyst, and a nickel catalyst-enabled acceptorless dehydrogenation of hydrocarbons is reported. The cationic nickel complex played a critical role in the reactivity. This is the first example of acceptorless dehydrogenation of hydrocarbons by base metal catalysis under mild reaction conditions of visible light irradiation at room temperature.
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