期刊
ORGANIC LETTERS
卷 20, 期 4, 页码 942-945出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03837
关键词
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资金
- National Research Foundation of Korea (NRF) grants - Korean government (MSIP) [NRF-2015R1A5A1008958, NRF-2015R1C1A2A01053504]
A rhodium-catalyzed decarbonylative aerobic oxidation of cyclic alpha-diketones has been developed for the first time, where the regioselective formations of alpha-pyrones and isocoumarins have been achieved. The current decarbonylative aerobic oxidation pathway proceeds via the C-C bond cleavage followed by a C-O bond formation, representing a biomimetic oxidation approach to unsaturated six-membered cyclic lactones. The unique ability of rhodium catalysts to induce the decarbonylative aerobic oxidation opens up a new synthetic toolbox that utilizes the regioselective single carbon extrusion strategy.
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