期刊
ORGANIC LETTERS
卷 20, 期 4, 页码 1031-1033出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03979
关键词
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资金
- JSPS KAKENHI [JP24590136, JP16K08180]
- Grants-in-Aid for Scientific Research [16K08180] Funding Source: KAKEN
In this work, the protecting-group-free total synthesis and stereochemical assignment of (-)-boscartin F have been reported. The key steps, including Sharpless asymmetric epoxidation, I-2-mediated iodoetherification, aldol reaction, and ring-closing metathesis, allowed for rapid and highly stereoselective access to boscartin F. In addition, single-crystal X-ray crystallographic analysis of the semicarbazone derivative 22 confirmed the stereochemistry of boscartin F.
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