期刊
ORGANIC LETTERS
卷 20, 期 8, 页码 2481-2484出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00847
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资金
- New Energy and Industrial Technology Development Organization (NEDO)
A nickel complex/Lewis acid combination effectively catalyzed the direct silyl Heck reaction of chlorosilanes, which are key raw materials in the organosilicon industry, to give synthetically important alkenylsilane products. Trichlorosilanes, dichlorosilanes, and monochlorosilanes underwent the silyl Heck reaction to afford the corresponding alkenylsilanes in high yields. In the reactions of dichlorosilanes, a single substitution occurred to give monoalkenylsilanes in a highly selective manner.
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