期刊
ORGANIC LETTERS
卷 20, 期 8, 页码 2433-2436出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00778
关键词
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资金
- NSF [CHE-1464744]
- National Natural Science Foundation of China [21708020]
- Natural Science Foundation of Jiangsu Provence [BK20170969]
A novel carbanionic reactivity of imines mediated by photoredox catalysis is demonstrated. The umpolung imine reactivity is exemplified by proton abstraction from water as a key step in the reduction of benzophenone ketimines to amines (up to 98% yield). Deuterium is introduced into amines efficiently using D2O as an inexpensive deuterium source (>= 95% D ratio). The mechanism of this unusual transformation is probed.
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