期刊
ORGANIC LETTERS
卷 20, 期 8, 页码 2338-2341出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00681
关键词
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资金
- Spanish MINECO [CTQ2013-43310, CTQ2017-84249-P]
- Generalitat Valenciana [PROMETEOII/2014/073]
- National Institutes of Health [R01GM121660]
- Spanish Government
- Generalitat Valenciana
A simple, user-friendly, metal-free protocol for the regioselective anti-Markovnikov hydrofluorination of olefins using readily available and inexpensive reagents has been developed. This new approach displays a broader scope than previously reported methodologies and has been applied to the late-stage fluorination of a complex molecule, giving rise to a fluorosteroid derivative. The stereochemistry of the process has also been studied in some detail.
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