期刊
ORGANIC LETTERS
卷 20, 期 8, 页码 2278-2281出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00622
关键词
-
资金
- National Natural Science Foundation of China [21202109, 21772135]
- Sichuan Normal University [16ZP10, ZZYQ2017004, DJGX2017004, DJGX2017005]
An efficient protocol to synthesize unsymmetrical triphenylenes from electron-rich biphenyls and diaryliodonium salts via Cu catalysis was developed. A variety of unsymmetrical triphenylenes with diversified functional groups were synthesized according to this method. This transformation went through multiple direct C-H arylations from easily produced starting materials with high step-economy. The gram-scale synthesis of triphenylenes and their facile transformation into diverse functional organic molecules were illustrated.
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