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ORGANIC LETTERS
卷 20, 期 4, 页码 983-986出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03916
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资金
- NSFC [21332003]
An enantioselective Rh(II)/chiral phosphoric acid co-catalyzed three-component reaction via trapping of oxonium ylides with 3-hydroxyisoindolinones by a formal S(N)1 pathway is described. This reaction allows for the efficient synthesis of isoindolinone derivatives with two contiguous quaternary stereogenic centers in high yields (up to 93%) with excellent enantioselectivities and moderate diastereoselectivities under mild reaction conditions.
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