期刊
ORGANIC ELECTRONICS
卷 54, 期 -, 页码 197-203出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.orgel.2017.12.050
关键词
Solution-processed; Iridium complex; Yellow/orange emission; Organic light-emitting diode; Ancillary ligands
资金
- National Key Basic Research and Development Program of China (973 program) [2015CB655001, 2014CB643504]
- National Natural Science Foundation of China [51473162, 51773195, 51325303, 21334006]
- Chinese Academy of Sciences [XDB12030200]
- Hong Kong Research Grants Council [HKBU 12304715]
- Areas of Excellence Scheme, University Grants Committee of HKSAR [AoE/P-03/08]
- Hong Kong Polytechnic University [1-ZE1C]
- State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
Efficient solution-processible yellow/orange emissive phosphors are highly required in solution-processed phosphorescent organic light-emitting diodes (s-PhOLEDs). With respect to phenyl pyridine (ppy)-type Ir(III) complexes, 2-(9,9-diethylfluoren-2-yl) pyridine (Flpy)-type Ir(III) complexes have huge potential in yellow/orange s-PhOLEDs due to their extended conjugation and excellent solubility in common organic solvents. Herein, a new series of phosphorescent Ir(III) complexes, i. e. Ir(Flpy)(2)pic-NeO, Ir(Flpy-CF3)(2)pic-NeO, Ir(Flpy-CF3)(2)dbm and Ir(Flpy-CF3)(2)acac, based on Flpy main ligand and picolinic N-oxide (pic-NeO), acetylacetone (acac), and dibenzoyl methane (dbm) ancillary ligands are synthesized. The photophysical, electrochemical, and electroluminescent (EL) properties of these phosphorescent Ir(III) complexes are investigated in details. By introducing the CF3 group in Flpy ligand and varying the ancillary ligands, the emission spectra of these phosphorescent complexes are tuned in a large range with EL emission peaks from 544 nm to 588 nm. The s-PhOLEDs employing these phosphors show promising EL performance with maximum external quantum efficiency (EQE) from 15.4% to 23.7% and high power efficiency from 61.9 l m W-1 to 80.4 l m W-1. These highly efficient phosphorescent Ir (III) complexes may serve as ideal chromaticity components in solution-processed full-color displays and lighting devices.
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