期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 16, 期 26, 页码 4816-4820出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob01034j
关键词
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资金
- National Natural Science Foundation of China [21302014, 21676030]
- China Postdoctoral Science Foundation funded project [2018M632289]
- Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology [BM2012110]
- Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions
- Advanced Catalysis and Green Manufacturing Collaborative Innovation Center of Changzhou University
A nickel-catalyzed cyanation of phenol derivatives activated by 2,4,6-trichloro-1,3,5-triazine (TCT) using aminoacetonitrile as the cyanating agent is described. This catalytic system delivered the desired products in moderate to good yields with good substrate compatibility. The readily available starting materials, cost-effective nickel catalyst and metal-free cyanating agent are the major features of the present method.
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