期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 16, 期 14, 页码 2402-2405出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob00207j
关键词
-
资金
- National Natural Science Foundation of China [81602995]
A palladium-catalyzed intramolecular C(sp(2))-H amination of phenylalanine moieties in dipeptides is described. By this protocol, a series of indoline-2-carboxylate-containing dipeptides were synthesized from dipeptides. The N-protected amino acid moiety within the peptide is used as an intrinsic bidentate directing group. This intramolecular C-H amination reaction provides an appealing strategy for the post-synthetic modification of peptides.
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