期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 16, 期 16, 页码 2893-2901出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob00359a
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资金
- Fundamental Research Funds for the Central Universities in China [CQDXWL-2014-Z003]
- Scientific Research Foundation of China [21402016, 21602023]
- Graduate Scientific Research and Innovation Foundation of Chongqing, China [CYS17044, CYB16032]
An organo-catalyzed enantioselective addition of selenosulfonates to alpha,beta-unsaturated ketones was developed for the first time. With a chiral squaramide as an efficient catalyst, the desired alpha-selenylated ketones were obtained in a good yields with high enantioselectivity up to 89% ee, and good results could be obtained on a gram scale. The products could also be efficiently transformed into useful building blocks with a propenylic stereocenter; the strategy presented in this study may find further applications in organic synthesis.
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