4.6 Article

Recyclable cellulose-palladium nanoparticles for clean cross-coupling chemistry

期刊

ORGANIC & BIOMOLECULAR CHEMISTRY
卷 16, 期 15, 页码 2748-2752

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob00527c

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  1. National Science Foundation [CHE-1401700]
  2. Institute of Molecular Diversity and Drug Design (IMD3) of the University of Louisville
  3. Direct For Mathematical & Physical Scien
  4. Division Of Chemistry [1401700] Funding Source: National Science Foundation

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Cheap, recyclable, and robust cellulose-palladium nanoparticles were developed and fully characterized by FTIR, TEM, XPS, TGA, and NMR. The nanoparticles enabled cross-coupling chemistry in a truly general fashion i.e., Suzuki-Miyaura, Heck, Sonogashira, and C-H activation. Notably, all types of transformations were achieved with a single type of nanocatalyst Complete recyclability of the catalyst and low traces of palladium in the product demonstrates the greenness of the protocol.

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