期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 16, 期 4, 页码 510-520出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob02615c
关键词
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资金
- Natural Science Foundation of China [21390400, 21521002, 21502198, 21572232]
- Chinese Academy of Science [QYZDJ-SSW-SLH023]
- National Program of Top-notch Young Professionals
Enantioselective protonation, delivery of a proton to a carbanion intermediate, is the most straightforward and fundamental method for the preparation of a chiral tertiary carbon stereocenter. Recent efforts for this objective have been realized through enamine catalysis, which has now become a prominent catalytic strategy enabling a range of fascinating chiral transformations. This review will summarize recent advances in the field of enantioselective enamine protonation for the synthesis of optically active carbonyl compounds. Dynamic kinetic resolutions of alpha-substituted carbonyl compounds through enamine intermediates will be discussed as well.
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