期刊
CHEMICAL PAPERS
卷 67, 期 9, 页码 1240-1244出版社
SPRINGER INTERNATIONAL PUBLISHING AG
DOI: 10.2478/s11696-013-0386-9
关键词
oxidations; alcohols; hydrogen peroxide; polyoxymetalate; microwaves
This work deals with catalytic activity of tetrabutylammonium decatungstate(VI) in the oxidation of selected alcohols with hydrogen peroxide as an oxidant using 1,2-dichloroethane/water or acetonitrile/water as a solvent system. Different forms of heating were compared. The highest conversions of substrates were achieved in the two phase system acetonitrile/water using microwave irradiation combined with elevated pressure. Finally, optimum parameters for these reactions in a microwave pressurised reactor were established and discussed. (C) 2013 Institute of Chemistry, Slovak Academy of Sciences
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