期刊
OPTICAL MATERIALS
卷 80, 期 -, 页码 65-70出版社
ELSEVIER
DOI: 10.1016/j.optmat.2018.04.040
关键词
Poly(ethylene-co-acrylic acid); Polymer-rare earth complex; Fluorescent properties; Film
资金
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), China
- National Research Foundation of Korea [2015K2A1A2069191]
A series of novel polymer-rare earth complexes with Eu3+ ions have been synthesized and investigated successfully, including the binary complexes containing the single ligand poly(ethylene-co-acrylic acid) (EAA) and the ternary complexes using 1,10-phenanthroline (phen), dibenzoylmethane (DBM) or thenoyltrifluoroacetone (TTA) as the second ligand. Their structures have been characterized by Fourier transform infrared spectroscopy (FT-IR), elemental analysis and X-ray diffraction (XRD), which confirm that both EAA and small molecules participate in the coordination reaction with rare earth ions, and they can disperse homogeneously in the polymer matrixes. Both ultraviolet visible (UV-vis) absorption and photoluminescence tests for the complexes have been recorded. The relationship between fluorescence intensity of polymer-rare earth complexes and the quantity of ligand EAA has been studied and discussed. The films casted from the complexes solution can emit strong characteristic red light under UV light excitation. All these results suggest that the complexes possess potential application as luminescent materials.
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