期刊
NEW JOURNAL OF CHEMISTRY
卷 42, 期 2, 页码 1396-1402出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nj04129b
关键词
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资金
- Thailand Research Fund [RTA 6080005]
- Thailand Research Fund and Faculty of Science, Silpakorn University [RSA 6080058]
- DPST Research Grant [005/2557]
- Thailand Graduate Institute of Science and Technology (TGIST) from National Science and Technology Development Agency (NSTDA), Thailand [TG-33-16-59-012D]
A visually colorimetric'' and fluorometric sensor based on [5] helicene connected to rhodamine 6G via a hydrazide moiety, RG5H, was designed and prepared for the highly sensitive and selective detection of Hg2+. The sensor system operated through the FRET process from the [5] helicene energy donor to the ring-opened rhodamine 6G-Hg2+ complex acceptor. The sensor illustrated a very large Stokes shift up to 176 nm. In aqueous acetonitrile solutions, RG5H exhibited high selectivity and sensitivity toward Hg2+ in the presence of various competitive metal ions, such as Cu2+, Ag+, Zn2+, Pb2+, Ca2+, Cd2+, Co2+, Fe2+, Mg2+, Mn2+, Ba2+, Ni2+, Na+, Li+ and K+. The detection limit of RG5H for determination of Hg2+ was found to be 2.3 ppb. The binding of RG5H to Hg2+ was evident in both fluorescence enhancement as well as a colorimetric change in the sensor from greenish-yellow to orange, which could be easily observed by the naked eye.
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