期刊
NEW JOURNAL OF CHEMISTRY
卷 42, 期 12, 页码 10348-10356出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nj01278d
关键词
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资金
- National Natural Science Foundation of China [51373070]
- Fundamental Research Funds for the Central Universities [JUSRP51624A]
- MOE & SAFEA, 111 Project [B13025]
- China Scholarship Council (CSC) [CSC N201706790065]
- Innovation Project for College Graduates of Jiangsu Province [KYLX16_0784]
- Joint Pre-research Foundation of Ministry of Education of China [6141A02022228]
- National First-Class Discipline Program of Light Industry Technology and Engineering [LITE2018-19]
Herein, high-performance and self-healing poly(epsilon-caprolactone) (PCL) nanocomposites were fabricated using polydopamine-capped reduced graphene oxide (PDG) as a nanofiller with the aid of fold-thermal compression (termed mechanical annealing) cycle effect. To improve the dispersion and interfacial interactions between the PDG nanosheets and PCL matrix, PCL chains were first grafted on PDG nanosheets by ring-opening polymerization of epsilon-caprolactone. Notably, superior mechanical performances were successfully achieved by tailoring the periodic mechanical annealing process. The tensile strength of the PCL nanocomposite reaches up to 41.6 MPa, and the yield strength is as high as 22.7 MPa after 10 cycles of mechanical annealing, which are 2.4 and 2.6 times higher than those of pure PCL, respectively. Moreover, the photothermal conversion ability of polydopamine endowed the nanocomposite with self-healing functionality. The temperature of nanocomposites can rapidly surpass the melting temperature of the polymer upon exposure to near-infrared (NIR) light and thus allows fast NIR light-induced self-healing and recovery of the mechanical properties of the nanocomposites; this finding provides a facile method to obtain and explore new graphene-based NIR light-induced self-healing nanocomposites.
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