期刊
NEW JOURNAL OF CHEMISTRY
卷 42, 期 1, 页码 260-264出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nj03212a
关键词
-
资金
- Fondecyt [11140172, 1150759]
- project ICM-MINECON - Fondo de Innovacion para La Competitividad Del Ministerio de Economia, Fomento y Turismo, Chile [RC-130006 - CILIS]
- Instituto de Ciencias e Innovacion en Medicina (ICIM-CAS UDD)
- [3120060]
The reaction of 2,4-dinitrobenzenesulfonyl chloride toward propylamine was kinetically evaluated in 19 organic solvents and 10 ionic liquids as reaction media. This study was compared with a previous study to experimentally show that solvent effects and the nature of the reacting pair drastically affect the reaction rate and the reaction mechanism. While the reaction of the reference electrophile 2,4-dinitrobenzenesulfonyl chloride with piperidine is favored in polar solvents with the ability to donate or accept hydrogen bonds, the reaction with propylamine is favored in solvents with the ability to accept hydrogen bonds.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据