期刊
NEW JOURNAL OF CHEMISTRY
卷 42, 期 9, 页码 7254-7261出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nj04941b
关键词
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资金
- Shanxi Province Foundation [2015021038, MC2014-01]
- National Natural Science Foundation of China (NSFC) [91545116]
Designing cost-effective, highly efficient and stable electrocatalysts for oxygen evolution reaction is of paramount importance. Although extensive studies have focused on the relatively cheaper 3d transition metal oxide catalysts, the effect of trimetallic composites on the catalytic ability still remains elusive. Herein, we selected FeCo catalyst as the platform and investigated the catalytic activity of trimetallic composites, which were synthesized by incorporating Mo, W or Ni into the FeCo catalyst. The experimental results evidenced that FeCoMo/CP exhibited high catalytic activity towards water oxidation in alkaline solution, which required an overpotential of only similar to 270 mV. Such impressive catalytic performance of FeCoMo/CP can be attributed to the fact that the introduction of Mo appreciably modulated the electronic structure of the Fe and Co centers, leading to an enhancement in intrinsic active sites. Benefiting from the tight contact with the highly conductive carbon paper substrate, FeCoMo/CP showed excellent stability up to 120 h. These results indicate that the surface engineering of FeCo-based catalysts by incorporating non-noble metals is a rational strategy to promote the performance of electrocatalysts.
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