期刊
NANOSCALE
卷 10, 期 29, 页码 14005-14011出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nr03739f
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资金
- National Natural Science Foundation of China [21674106]
- CAS Youth Innovation Promotion Association [2015365]
- Fundamental Research Funds for the Central Universities [WK3450000004]
Precise arrangement of the aromatic donor-acceptor units is of paramount importance to dictate the performance of multi-component pi-functional materials. Herein a novel strategy has been developed toward alternate donor-acceptor copolymers, by incorporating Pt(II)center dot center dot center dot Pt(II) metal-metal interactions for the hetero-complexation process. The proximity of Pt atoms endows the resulting supramolecular copolymers with metal-metal-to-ligand charge-transfer transitions in the visible/NIR region. The signals have been further applied for low-energy visible-light photo-catalysis that is unattainable for the individual species. More interestingly, on-demand photo-catalytic efficiency can be achieved by manipulating the reversibility of the supramolecular copolymerization process. Hence, the current work demonstrates the efficiency of fabricating multi-component pi-functional materials via the elaborate manipulation of non-covalent driving forces.
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