期刊
NANOSCALE
卷 10, 期 24, 页码 11335-11341出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nr00660a
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资金
- Center of Excellence (STIM) at the University of Split
- STIM-REI - European Union from European Structural and Investment Funds [KK.01.1.1.01.0003]
- National Science Centre [DEC-2013/10/A/ST4/00114, DEC-2013/09/B/ST5/03417]
- Polish Ministry of Science and Higher Education
- French-Croatian project International Laboratory for Nano Clusters and Biological Aging, LIA NCBA
- Royal Society Wolfson Research Merit Award
Thiolate-protected gold nanoclusters have recently attracted considerable attention due to their size-dependent luminescence characterized by a long lifetime and large Stokes shift. However, the optimization of nanocluster properties such as the luminescence quantum yield is still a challenge. We report here the transformation of Au(25)Capt(18) (Carat labels captopril) nanoclusters occurring at low pH and yielding a product with a much increased luminescence quantum yield which we have identified as Au(23)Capt(17). We applied a simple method of treatment with HCl to accomplish this transformation and we characterized the absorption and emission of the newly created ligated nanoclusters as well as their morphology. Based on DFT calculations we show which Au nanocluster size transformations can lead to highly luminescent species such as Au(23)Capt(17).
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