期刊
NANO LETTERS
卷 18, 期 3, 页码 1758-1763出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.nanolett.7b04889
关键词
Aqueous zinc-ion battery; Na2V6O16 center dot 1.63H(2)O; nanowire; single-nanowire battery; zinc ion intercalation and deintercalation
类别
资金
- National Natural Science Fund for Distinguished Young Scholars [51425204]
- National Natural Science Foundation of China [51521001, 21673171, 51502226]
- National Key Research and Development Program of China [2016YFA0202603]
- Programme of Introducing Talents of Discipline to Universities [B17034]
- Fundamental Research Funds for the Central Universities [WUT: 2016III001, 2016III002, 2017III009, 2017III008, 2016III012]
Rechargeable aqueous zinc-ion batteries are highly desirable for grid-scale applications due to their low cost and high safety; however, the poor cycling stability hinders their widespread application. Herein, a highly durable zinc-ion battery system with a Na2V6O16 center dot 1.63H(2)O nanowire cathode and an aqueous Zn(CF3SO3)(2) electrolyte has been developed. The Na2V6O16 center dot 1.63H(2)O nanowires deliver a high specific capacity of 352 mAh g(-1) at 50 mA g(-1) and exhibit a capacity retention of 90% over 6000 cycles at 5000 mA g(-1), which represents the best cycling performance compared with all previous reports. In contrast, the NaV3O8 nanowires maintain only 17% of the initial capacity after 4000 cycles at 5000 mA g(-1). A single-nanowire-based zinc-ion battery is assembled, which reveals the intrinsic Zn2+ storage mechanism at nanoscale. The remarkable electrochemical performance especially the long-term cycling stability makes Na2V6O16 center dot 1.63H(2)O a promising cathode for a low-cost and safe aqueous zinc-ion battery.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据