期刊
HETEROCYCLES
卷 91, 期 3, 页码 479-504出版社
Japan Inst Heterocyclic Chemistry
DOI: 10.3987/REV-14-816
关键词
Substituted Pyridine; Lithium Reagent; Directed Lithiation; Directing Metalating Group; Electrophile
资金
- Deanship of Scientific Research at King Saud University [RGP-VPP-239]
Directed lithiation of substituted pyridines containing a directing metalating group (DMG) with a lithium reagent in anhydrous solvent at low temperature gives the corresponding lithium intermediates in-situ, which on reactions with electrophiles produce the corresponding substituted derivatives. The method is simple, general, convenient and often high yielding.
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