期刊
MOLECULES
卷 23, 期 4, 页码 -出版社
MDPI
DOI: 10.3390/molecules23040792
关键词
carbenes; porphyrins; metalloporphyrins; cyclopropanation; cyclopropenation; olefination; X-H insertion
资金
- Portuguese Science and Technology Foundation (FCT) [FCT UID/QUI/00062/2013]
- European Union [FCT UID/QUI/00062/2013]
- QREN [FCT UID/QUI/00062/2013]
- FEDER [FCT UID/QUI/00062/2013]
- COMPETE [FCT UID/QUI/00062/2013]
- FCT [SFRH/BPD/79521/2011]
- FAPERJ
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES)
- Fundacao de Amparo a Pesquisa do Estado do Rio de Janeiro (FAPERJ)
- Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq)
Carbene transfer reactions are very important transformations in organic synthesis, allowing the generation of structurally challenging products by catalysed cyclopropanation, cyclopropenation, carbene C-H, N-H, O-H, S-H, and Si-H insertion, and olefination of carbonyl compounds. In particular, chiral and achiral metalloporphyrins have been successfully explored as biomimetic catalysts for these carbene transfer reactions under both homogeneous and heterogeneous conditions. In this work the use of synthetic metalloporphyrins (MPorph, M = Fe, Ru, Os, Co, Rh, Ir, Sn) as homogeneous or heterogeneous catalysts for carbene transfer reactions in the last years is reviewed, almost exclusively focused on the literature since the year 2010, except when reference to older publications was deemed to be crucial.
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