期刊
MOLECULES
卷 23, 期 6, 页码 -出版社
MDPI
DOI: 10.3390/molecules23061255
关键词
direct arylation; organic electronics; organic thin film transistors; organic photovoltaics; green chemistry
资金
- Natural Sciences and Engineering Research Council (NSERC) of Canada [RGPIN-2016-04366]
- MDPI
C-C bond forming reactions are central to the construction of pi-conjugated polymers. Classical C-C bond forming reactions such as the Stille and Suzuki coupling reactions have been widely used in the past for this purpose. More recently, direct (hetero) arylation polymerization (DHAP) has earned a place in the spotlight with an increasing number of pi-conjugated polymers being produced using this atom-economic and more sustainable chemistry. As semiconductors in organic electronics, the device performances of the polymers made by DHAP are of great interest and importance. This review compares the device performances of some representative pi-conjugated polymers made using the DHAP method with those made using the conventional C-C bond forming reactions when they are used as semiconductors in organic thin film transistors (OTFTs) and organic photovoltaics (OPVs).
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