期刊
MATERIAL DESIGN, PROCESSING AND APPLICATIONS, PARTS 1-4
卷 690-693, 期 -, 页码 1524-+出版社
TRANS TECH PUBLICATIONS LTD
DOI: 10.4028/www.scientific.net/AMR.690-693.1524
关键词
strontium-barium hydroxyapatite; coprecipitation; effect of pH
资金
- National Science Foundation of China [50874081]
- Key Project of Hubei Provincial Department of Education [D200515005]
This paper reports a novel coprecipitation process for the preparation of strontium-barium hydroxyapatite [Sr5-xBax(PO4)(3)OH]. Strontium nitrate, barium nitrate and phosphoric acid were dissolved in water to form a homogeneous Sr-Ba-P aqueous solution. The samples were characterized by powder X ray diffraction, Fourier transformed infrared spectroscopy and scanning electron microscopy. The results showed that the barium phosphate [Ba-3(PO4)(2)] phase appeared at the samples prepared at the pH value lower than 12. A series of Sr5-xBax(PO4)(3)OH samples had beenobtained by adding sodium hydroxide aqueous solution into the Sr-Ba-P solution to pH12.5 and following aging at 60 degrees C for 24h. The so-prepared samples are metallic cation-deficient hydroxyapatite solid solutions. The samples present low degree of crystallinity, irregular short rod-like morphology and nanometer size. The crystal cell parameters of Ca5-xSrx(PO4)(3)OH samples are nearly linear to their barium content, and their infrared absorption bands of PO43- groups shift to lower wave numbers with the increase of the barium content.
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