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Recent Advance of Allylic Alcohol Reagents in Organic Synthesis

期刊

MINI-REVIEWS IN ORGANIC CHEMISTRY
卷 15, 期 6, 页码 476-487

出版社

BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1570193X15666180220125122

关键词

Allylic alcohol; allylation; transition-metal catalyzed; activation; regio-/stereo-selective; aldehydes; ketones

资金

  1. National Natural Science Foundation of China [21562004]
  2. Jiangxi Education Hall Science and Technology Foundation [GJJ150944, GJJ160992]
  3. Jiangxi Health Hall Science and Technology Foundation [2013A043]
  4. Fundamental Research Funds for Gannan Medical University [QD201303, YB201415]

向作者/读者索取更多资源

Allylation reaction has been considered to be the most intriguing means for building collections of functionalized allylic compounds. The application of allylic alcohols for coupling reaction is complicated and typically summarized as four types such as they act as: allylation reagents, aldehyde/ketone sources, allylic ether reagents, and as allylic alcohol sources. The molecular insights enunciated herein allude to abundant opportunities for acting as allylation reagents as well as serving as aldehyde/ketone sources. It is our intent to propose that the domain of allylation reaction and the formation of aldehydes and ketones could enjoy additional benefits by having knowledge of the application of allylic alcohols in the organic synthesis.

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