期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 259, 期 -, 页码 244-254出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2017.10.018
关键词
Metal-Organic Framework; Methyl iodide adsorption; FTIR; Diffuse reflectance
类别
资金
- French State under the program Investissements d'Avenir called MIRE [ANR-11-RSNR-0013-01]
- Chevreul Institute [FR 2638]
- Ministere de l'Enseignement Superieur et de la Recherche
- Region Nord - Pas de Calais
- FEDER
- Institut Universitaire de France
In this work, methyl iodide (CH3I) sorption properties of Metal-Organic Frameworks (MOFs) were experimentally studied. CH3I adsorption capacities were determined at 35 degrees C for the different prototypical selected MOFs, MIL-53(Al), MIL-100(Al), MIL-120(Al), CAU-1(Al), UiO-66(Zr), HKUST-1(Cu) and ZIF-8(Zn) from fixed-bed reactor measurements by using infrared spectroscopy. Quantitative exploitation of breakthrough curves reveals higher sorption performances (Q(sat) up to 425 mg/g) for materials showing pore size and geometry well-adjusted to CH3I dimension, such as MIL-120(Al), MIL-53(Al) and HKUST-1(Cu). In situ DRIFTS (Diffuse Reflection Infrared Fourier Transform Spectroscopy) experiments were also carried out in order to further investigate the interaction modes of physisorbed CH3I species within MIL-53 and MIL-120 compounds. For MIL-120, the confinement of adsorbed mg molecules within the pores is strengthened by specific interactions with the ligand and hydroxyl groups. For a breathing compound like MIL-53(Al), the adsorption measurement confirmed a swelling related to CH3I adsorption.
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