期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 262, 期 -, 页码 199-206出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2017.11.044
关键词
V2O3@C core-shell nanorods; Porous structures; Amorphous carbon; Large specific surface area; Supercapacitor electrode; Device
类别
资金
- National Natural Science Foundation of China [21601026, 21771030]
- Fundamental Research Funds for the Central Universities [DUT16LK37]
- Doctoral Research Foundation of Liaoning Province [201601035]
V2O3@C core-shell nanorods with porous structures and large specific surface area were synthesized using V2O5 nanowires as the source of core and glucose as the source of shell by a facile hydrothermal route combination of heat treatment. As-prepared V2O3@C nanorods comprised of core-shell structures with crystalline V2O3 cores and amorphous carbon shells. Nitrogen adsorption-desorption isotherms revealed that V2O3@C core-shell nanorods displayed BET specific surface area as high as 219 m(2).g(-1) and had hierarchical porous structures. Electrochemical properties of V2O3@C core-shell nanorods as supercapacitor electrode were studied and showed their measured capacitance was based on the pseudocapacitance. Specific capacitances of V2O3@C core-shell nanorods measured 228, 221, 207, 158 and 127 F.g(-1) at current densities of 0.5, 1, 2, 5 and 10 kg(-1), respectively. Results showed V2O3@C core-shell nanorods displayed higher specific capacitance than values of carbon spheres (4 F.g(-1) at 1 kg(-1)) and V2O3 nanomaterials (49 F.g(-1) at 1 kg(-1)), Asymmetric supercapacitor device assembled from V2O3@C core-shell nanorods and activated carbon (V2O3@C//C) showed specific capacitances of 0.297, 0.274, 0.230, 0.194 and 0.169 F.cm(-2) at current densities of 0.5, 1, 2, 5 and 10 mA.cm(-2), respectively. It showed higher specific capacitance than that of V2O3//C device (0.219 F.cm(-2) at 1 mA.cm(-2)). A capacitance retention of 86% for V2O3@C//C device after 1000 cycles indicated that V2O3@C had good cycling performance for supercapacitor application. Present findings suggested that V2O3@C core-shell nanorods could be considered as potential materials for high-performance energy storage materials.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据