期刊
MATERIALS RESEARCH BULLETIN
卷 100, 期 -, 页码 254-258出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2017.12.045
关键词
Composites; Nanostructures; Electrochemical measurements; Electrochemical properties; Energy storage
A flexible carbon nanofiber membrane (NFM) containing uniformly dispersed MoO2 nanoparticles is facilely fabricated via electrospinning and subsequent controlled reduction-carbonization. This NFM is used directly as a binder-free anode in lithium-ion batteries (Ins). The self-standing carbon/MoO2 (C/MoO2) NFM electrode has a good capacity retention, a satisfactory rate capability and a high reversible capacity of 811 mAh g(-1) after 100 cycles at a current density of 100 mA g(-1), which is superior to most other MoO2-based anodes. The superior electrochemical properties of the resultant C/MoO2 NFM are attributed to the cooperative effects from the excellent conductivity of the carbon nanofiber matrix, the high electrochemical performance of MoO2, the unique one-dimensional nanofiber structure and the three-dimensional porous network structure. The present C/MoO2 NFM may be an attractive candidate as an anode material for LIBs.
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