期刊
MATERIALS LETTERS
卷 223, 期 -, 页码 73-77出版社
ELSEVIER
DOI: 10.1016/j.matlet.2018.04.024
关键词
Piezoelectric; PVDF; Magnetostrictive; CoFe2O4; Nanofiller; Magnetoelectric; Composites
资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2016R1C1B1010884]
In this study, we systematically investigated the effects of CoFe2O4 (CFO) nanofillers on the beta-phase formation of piezoelectric PVDF after solvent casting, thermal annealing, electrical poling, and uniaxial stretching, which are all essential steps in the fabrication of magnetoelectric composites. Therefore, zero-dimensional CFO nanoparticles and one-dimensional CFO nanorods were prepared as magnetostrictive nanofillers via hydrothermal synthesis. Among three-type films consisting of PVDF, PVDF/CFO nanoparticles, and PVDF/CFO nanorods, the beta-phase fractions of PVDF were found to exhibit the maximum values of 47.1 after poling and 78.5% after stretching, in the films of PVDF/CFO nanoparticles. These results illustrated that the shape and size of CFO nanofillers are very important for the design of polymer-based magnetoelectric composites, because the nanofillers are beneficial to provide a physical barrier that helps maintain parallel dipoles of the beta-phase, while simultaneously playing the negative role of conductors to induce electrical percolation. (C) 2018 Elsevier B.V. All rights reserved.
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