期刊
MATERIALS CHEMISTRY AND PHYSICS
卷 217, 期 -, 页码 63-73出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2018.06.051
关键词
Sc-and non-doped ZnO sodalite like cage; Small gases adsorption; DFT; NBO charge
资金
- Ratchadaphiseksomphot Endowment Fund of Chulalongkorn University [RES560530016-AM]
Structure optimizations for adsorption configurations of di-, tri- and polyatomic gases on Sc-doped ZnO sodalite like cage (Sc-ZnOSL) were carried out using the DFT/B3LYP/GEN method. Energetics, enthalpies and Gibbs free energies of gas adsorptions were obtained. Adsorption of SO2 on the Sc-ZnOSL was found to be the most energetically preferred configuration. Since, energy gaps for the Sc-ZnOSL and its adsorption-state structures were analyzed as a function of electric conductivity, it was found that the largest decrease of energy gap was taken placed after bridge-structured adsorption of N2O on the Sc-ZnOSL. The suggestion is that Sc-ZnOSL may be developed for N2O and SO(2)sensing material.
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