期刊
ACS APPLIED MATERIALS & INTERFACES
卷 7, 期 12, 页码 6574-6583出版社
AMER CHEMICAL SOC
DOI: 10.1021/am508711p
关键词
antimony doped tin oxide (ATO); mesoporous microspheres; methanol; solvothermal route; transparent thin films; solar-heat shielding
资金
- first-class discipline construction plan in Shanghai University
- PCSIRT [IRT1269]
- Shanghai Science & Technology Committee [12521102501]
- Shanghai Educational Committee [11ZR1426500, 14ZZ127]
- Program of Shanghai Normal University [DZL124]
In this paper, mesoporous antimony doped tin oxide (ATO) microspheres are synthesized via a solvothermal method from a methanol system with the surfactant followed by a thermal treatment process. Morphology studies reveal that the spherical products obtained by polyvinylpyrrolidone (PVP) templating result in a higher uniformity in size. Such obtained ATO microspheres with a secondary particle size ranging between 200 and 800 nm consist of packed tiny nanocrystals and have high specific surface area (similar to 98 m(2) g(-1)). The effect of Sb doping on the structural and electrical properties of SnO2 microspheres is studied. Because of the substitution of Sn4+ with Sb5+ accompanied by forming a shallow donor level close to the conduction band of SnO2, a lower resistivity of powder pellet can be achieved, which corresponds to the spectrally selective property of films. The application of ATO microspheres provides an example of transparent coatings; depending on Sb concentration in SnO2 and solid content of coatings, transparent films with tunable solar-heat shielding property are obtained.
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