期刊
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
卷 15, 期 5, 页码 1015-1022出版社
SPRINGER
DOI: 10.1007/s13738-018-1298-y
关键词
Sensor; Electrodeposition; Chitosan; Hydrogen peroxide; Silver nanoparticles
资金
- Hakim Sabzevari University Research Council
We studied a rapid, sensitive and selective amperometric sensor for determination of hydrogen peroxide by electrodeposited Ag NPs on a modified glassy carbon electrode (GCE). The modified GCE was constructed through a step by step modification of magnetic chitosan functional composite (Fe3O4-CH) and high-dispersed silver nanoparticles on the surface. The resulted Ag@Fe3O4-CH was characterized by various analytical methods including Fourier transform infrared spectroscopy, X-ray diffraction, transmission electron microscopy, scanning electron microscopy and cyclic voltammetry. The proposed sensor employed Ag@Fe3O4-CH/GCE as the working electrode with a linear current response to the hydrogen peroxide concentration in a wide range from 0.01 to 400 mu M with a low limit of detection (LOD = 0.0038 mu M, S/N = 3). The proposed sensor showed superior reproductivity, sensitivity and selectivity for the detection of hydrogen peroxide in environmental and clinical samples.
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