期刊
出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.egypro.2013.08.028
关键词
Power to gas; CO2-Methanation; Sabatier; reaction; flue gas
The hydrogenation CO2 + 4H(2) -> CH4 + 2H(2)O discovered by Paul Sabatier nowadays is discussed as Power-to-Gas approach to utilize excess energy from renewable electricity generation. in a laboratory scale, we investigate the Sabatier process in a simulated flue gas atmosphere of conventional base load power plants. The reaction is investigated with regard to conversion rates, yield, selectivity and long-term stability. Using a catalyst based on nickel, we extract selectivities near 100% with a conversion around 85%. Beside the influence of oxygen, we investigate further typical contaminations like NO2 and SO2. (C 2013 The Authors. Published by Elsevier Ltd.
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